Hyperfine components of all rovibrational quadrupole transitions in the H$_{2}$ and D$_{2}$ molecules
Abstract
We report results of a theoretical investigation of hyperfine interactions in two homonuclear isotopologues of the hydrogen molecule: H and D. We present a set of hyperfine coupling constants: spin-rotation, spin-spin dipole and, in the case of the D molecule, electric quadrupole coupling constants for all bound states of the two isotopologues in their ground electronic state. We provide a list of positions and intensities of 220 997 hyperfine components of 16 079 rovibrational quadrupole transitions of the O, Q and S branches. The positions and intensities of the hyperfine components are necessary for a reliable interpretation of accurate measurements of rovibrational transition frequencies in H and D, which are used for tests of the quantum electrodynamics of molecules and searches for new physics beyond the Standard Model.
Keywords
Cite
@article{arxiv.2006.05717,
title = {Hyperfine components of all rovibrational quadrupole transitions in the H$_{2}$ and D$_{2}$ molecules},
author = {Hubert Jóźwiak and Hubert Cybulski and Piotr Wcisło},
journal= {arXiv preprint arXiv:2006.05717},
year = {2020}
}