High-pressure synthesis of boron-rich chalcogenides B12S and B12Se

Kirill A. Cherednichenko; Vladimir A. Mukhanov; Aleksandr Kalinko; Vladimir L. Solozhenko

doi:10.1016/j.jallcom.2021.162874

High-pressure synthesis of boron-rich chalcogenides B12S and B12Se

Materials Science 2022-01-10 v1

Authors: Kirill A. Cherednichenko , Vladimir A. Mukhanov , Aleksandr Kalinko , Vladimir L. Solozhenko

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Abstract

Two boron-rich chalcogenides B12S and B12Se isostructural to {\alpha}-rhombohedral boron were synthesized by chemical reaction of the elements at high-pressure - high-temperature conditions. The crystal structures and stoichiometries of both compounds were confirmed by Rietveld refinement and elemental analysis. The experimental Raman spectra of B12S and B12Se were investigated for the first time. All observed Raman bands have been attributed to the theoretically calculated phonon modes, and the mode assignment has been performed.

Keywords

high-pressure synthesis boron-rich chalcogenides b12s b12se crystal structure raman spectra rietveld refinement

Cite

@article{arxiv.2105.04450,
  title  = {High-pressure synthesis of boron-rich chalcogenides B12S and B12Se},
  author = {Kirill A. Cherednichenko and Vladimir A. Mukhanov and Aleksandr Kalinko and Vladimir L. Solozhenko},
  journal= {arXiv preprint arXiv:2105.04450},
  year   = {2022}
}

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