Helium Multiplet Structure in Relativistic Schr\"odinger Theory
Abstract
The emergence of a multiplet structure of the helium-like ions is studied within Relativistic Schr\"odinger Theory (RST), a fluid-dynamic approach to the relativistic quantum theory of the many-particle systems. The fluid-dynamic character of RST demands to specify the electronic current densities for any -particle configuration which is exemplified here by considering the helium singlet () and triplet () states in great detail. Since the use of densities in RST is based upon the concept of wave functions, the new theory appears as a certain kind of (relativistic) unification of the conventional wave function formalism and the density functional theory, which both are the most prominent theoretical tools in atomic and molecular physics. As a demonstration of the practical usefulness of RST, the energy difference of the helium singlet states and is calculated for a large range of nuclear charge numbers (), whereas the corresponding experimental values are available only up to (molybdenum). The deviations of these RST results from the observational data is less than $0,3
Cite
@article{arxiv.physics/0602087,
title = {Helium Multiplet Structure in Relativistic Schr\"odinger Theory},
author = {R. Graebeldinger and T. Beck and M. Mattes and M. Sorg},
journal= {arXiv preprint arXiv:physics/0602087},
year = {2007}
}
Comments
84 pages, 2 figures