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Helium Multiplet Structure in Relativistic Schr\"odinger Theory

Atomic Physics 2007-05-23 v1

Abstract

The emergence of a multiplet structure of the helium-like ions is studied within Relativistic Schr\"odinger Theory (RST), a fluid-dynamic approach to the relativistic quantum theory of the many-particle systems. The fluid-dynamic character of RST demands to specify the electronic current densities \jmu\jmu for any NN-particle configuration which is exemplified here by considering the helium singlet (1S0{}^1S_0) and triplet (3S1{}^3S_1) states in great detail. Since the use of densities in RST is based upon the concept of wave functions, the new theory appears as a certain kind of (relativistic) unification of the conventional wave function formalism and the density functional theory, which both are the most prominent theoretical tools in atomic and molecular physics. As a demonstration of the practical usefulness of RST, the energy difference ΔE1\2\Delta E_{1\backslash 2} of the helium singlet states 2s21S02s^2 {}^1S_0 and 1s21S01s^2 {}^1S_0 is calculated for a large range of nuclear charge numbers zexz_{ex} (2zex1002\leq z_{ex}\leq 100), whereas the corresponding experimental values are available only up to zex=42z_{ex}=42 (molybdenum). The deviations of these RST results from the observational data is less than $0,3

Keywords

Cite

@article{arxiv.physics/0602087,
  title  = {Helium Multiplet Structure in Relativistic Schr\"odinger Theory},
  author = {R. Graebeldinger and T. Beck and M. Mattes and M. Sorg},
  journal= {arXiv preprint arXiv:physics/0602087},
  year   = {2007}
}

Comments

84 pages, 2 figures

R2 v1 2026-07-22T19:08:54.290Z