English

Ground state of many-electron systems based on the action function

Chemical Physics 2020-05-13 v1 Materials Science

Abstract

The Hilbert space for an interacting electron system increases exponentially with electron number NN. This limits the concept of wavefunctions ψ\psi based on solutions of the Schr\"odinger equation to NN0N \leq N_0 with N0103N_0 \simeq 10^3 \cite{Kohn1999}. It is argued that this exponential wall problem (EWP) is connected with an increasing redundance of information contained, e.g., in the ground-state of the system and it's wavefunction. The EWP as well as redundance of information are avoided when the characterization of the ground state is based on the action function RR rather than on the solutions ψ\psi of the Sch\"odinger equation. Both are related through a logarithm, i.e., R=i lnψR = -i \hbar \ ln \psi. Working with the logarithm is made possible by the use of cumulants. It is pointed out the way electronic structure calculations for periodic solids may use this concept.

Keywords

Cite

@article{arxiv.2005.03072,
  title  = {Ground state of many-electron systems based on the action function},
  author = {Peter Fulde},
  journal= {arXiv preprint arXiv:2005.03072},
  year   = {2020}
}

Comments

6 pages, 1 figure, simple solution of an old problem

R2 v1 2026-06-23T15:21:54.775Z