English

Frustration of freezing in a two dimensional hard-core fluid due to particle shape anisotropy

Soft Condensed Matter 2016-03-24 v1

Abstract

The freezing mechanism suggested for a fluid composed of hard disks [Huerta et al., Phys. Rev. E, 2006, 74, 061106] is used here to probe the fluid-to-solid transition in a hard-dumbbell fluid composed of overlapping hard disks with a variable length between disk centers. Analyzing the trends in the shape of second maximum of the radial distribution function of the planar hard-dumbbell fluid it has been found that the type of transition could be sensitive to the length of hard-dumbbell molecules. From the NpT{NpT} Monte Carlo simulations data we show that if a hard-dumbbell length does not exceed 15% of the disk diameter, the fluid-to-solid transition scenario follows the case of a hard-disk fluid, i.e., the isotropic hard-dumbbell fluid experiences freezing. However, for a hard-dumbbell length larger than 15% of disk diameter, there is evidence that fluid-to-solid transition may change to continuous transition, i.e., such an isotropic hard-dumbbell fluid will avoid freezing.

Keywords

Cite

@article{arxiv.1603.07147,
  title  = {Frustration of freezing in a two dimensional hard-core fluid due to particle shape anisotropy},
  author = {A. Huerta and D. Tejeda and D. Henderson and A. Trokhymchuk},
  journal= {arXiv preprint arXiv:1603.07147},
  year   = {2016}
}

Comments

9 pages, 7 figures