Formation and structure of the microemulsion phase in two-dimensional ternary AB+A+B polymeric emulsions
Soft Condensed Matter
2009-11-10 v1 Materials Science
Abstract
We present an analysis of the structure of the fluctuation-induced microemulsion phase in a ternary blend of balanced AB diblock copolymers with equal amounts of A and B homopolymers. To this end, graphical analysis methods are employed to characterize two-dimensional configuration snapshots obtained with the recently introduced Field-Theoretic Monte Carlo (FTMC) method. We find that a microemulsion forms when the mean curvature diameter of the lamellar phase coincides roughly with the periodicity of the lamellar phase. Further, we provide evidence to the effect of a subclassification of the microemulsion into a genuine and a defect-driven region.
Keywords
Cite
@article{arxiv.cond-mat/0405435,
title = {Formation and structure of the microemulsion phase in two-dimensional ternary AB+A+B polymeric emulsions},
author = {Dominik Düchs and Friederike Schmid},
journal= {arXiv preprint arXiv:cond-mat/0405435},
year = {2009}
}
Comments
to appear in J. Chem. Phys