English

Formation and structure of the microemulsion phase in two-dimensional ternary AB+A+B polymeric emulsions

Soft Condensed Matter 2009-11-10 v1 Materials Science

Abstract

We present an analysis of the structure of the fluctuation-induced microemulsion phase in a ternary blend of balanced AB diblock copolymers with equal amounts of A and B homopolymers. To this end, graphical analysis methods are employed to characterize two-dimensional configuration snapshots obtained with the recently introduced Field-Theoretic Monte Carlo (FTMC) method. We find that a microemulsion forms when the mean curvature diameter of the lamellar phase coincides roughly with the periodicity of the lamellar phase. Further, we provide evidence to the effect of a subclassification of the microemulsion into a genuine and a defect-driven region.

Keywords

Cite

@article{arxiv.cond-mat/0405435,
  title  = {Formation and structure of the microemulsion phase in two-dimensional ternary AB+A+B polymeric emulsions},
  author = {Dominik Düchs and Friederike Schmid},
  journal= {arXiv preprint arXiv:cond-mat/0405435},
  year   = {2009}
}

Comments

to appear in J. Chem. Phys