English

Fock expansion for two-electron atoms. High order angular coefficients

Atomic Physics 2022-10-14 v2

Abstract

The Fock expansion, which describes the properties of two-electron atoms near the nucleus, is studied. The angular Fock coefficients ψk,p(α,θ)\psi_{k,p}(\alpha,\theta) with the maximum possible value of subscript pp are calculated on examples of the coefficients with 5k105\leq k \leq 10. The presented technique makes it possible to calculate such angular coefficients for any arbitrarily large kk. The mentioned coefficients being leading in the logarithmic power series representing the Fock expansion may be indispensable for the development of simple methods for calculating the helium-like electronic structure. The theoretical results obtained are verified by other suitable methods. The Wolfram Mathematica is used extensively.

Keywords

Cite

@article{arxiv.2209.09053,
  title  = {Fock expansion for two-electron atoms. High order angular coefficients},
  author = {Evgeny Z. Liverts and Rajmund Krivec},
  journal= {arXiv preprint arXiv:2209.09053},
  year   = {2022}
}

Comments

27 pages

R2 v1 2026-06-28T01:39:35.133Z