English

Angular Fock coefficients. Fixing the errors, and further development

Atomic Physics 2015-05-12 v1 Mathematical Physics math.MP Computational Physics

Abstract

The angular coefficients ψk,p(α,θ)\psi_{k,p}(\alpha,\theta) of the Fock expansion characterizing the S-state wave function of the two-electron atomic system, are calculated in hyperspherical angular coordinates α\alpha and θ\theta. To solve the problem the Fock recurrence relations separated into the independent individual equations associated with definite power jj of the nucleus charge ZZ, are applied. The "pure" jj-components of the angular Fock coefficients, orthogonal to of the hyperspherical harmonics YklY_{kl}, are found for even values of kk. To this end, the specific coupling equation is proposed and applied. Effective techniques for solving the individual equations with simplest nonseparable and separable right-hand sides are proposed. Some mistakes/misprints made earlier in representations of ψ2,0\psi_{2,0}, were noted and corrected. All jj-components of ψ4,1\psi_{4,1} and the majority of components and subcomponents of ψ3,0\psi_{3,0} are calculated and presented for the first time. All calculations were carried out with the help of the Wolfram \emph{Mathematica}.

Keywords

Cite

@article{arxiv.1505.02351,
  title  = {Angular Fock coefficients. Fixing the errors, and further development},
  author = {Evgeny Z. Liverts and Nir Barnea},
  journal= {arXiv preprint arXiv:1505.02351},
  year   = {2015}
}

Comments

41 pages, 3 tables

R2 v1 2026-06-22T09:31:10.462Z