English

Fluctuation-induced pressures in fluids in thermal nonequilibrium steady states

Statistical Mechanics 2014-03-05 v2 Mesoscale and Nanoscale Physics

Abstract

Correlations in fluids in nonequilibrium steady states are long ranged. Hence, finite-size effects have important consequences in the nonequilibrium thermodynamics of fluids. One consequence is that nonequilibrium temperature fluctuations induce nonequilibrium Casimir-like pressures proportional to the square of the temperature gradient. Hence, fluctuations cause a breakdown of the concept of local thermal equilibrium. Furthermore, transport coefficients become dependent on boundary conditions and on gravity. Thus nonequilibrium fluctuations affect some traditional concepts in nonequilibrium thermodynamics.

Keywords

Cite

@article{arxiv.1401.1339,
  title  = {Fluctuation-induced pressures in fluids in thermal nonequilibrium steady states},
  author = {T. R. Kirkpatrick and J. M. Ortiz de Zárate and J. V. Sengers},
  journal= {arXiv preprint arXiv:1401.1339},
  year   = {2014}
}

Comments

15 pages, 3 figures, 1 table. Physical Review E, accepted