Recently large Rashba-like spin splitting has been observed in certain bulk ferroelectrics. In contrast with the relativistic Rashba effect, the chiral spin texture and large spin-splitting of the electronic bands depend strongly on the character of the band and atomic spin-orbit coupling. We establish that this can be traced back to the so-called orbital Rashba effect, also in the bulk. This leads to an additional dependence on the orbital composition of the bands, which is crucial for a complete picture of the effect. Results from first-principles calculations on ferroelectic GeTe verify the key predictions of the model.
@article{arxiv.1802.01546,
title = {First-principles theory of giant Rashba-like spin-splitting in bulk ferroelectrics},
author = {Louis Ponet and Sergey Artyukhin},
journal= {arXiv preprint arXiv:1802.01546},
year = {2018}
}