English

Finite-size effects and thermodynamic limit in one-dimensional Janus fluids

Statistical Mechanics 2021-10-29 v2 Soft Condensed Matter Chemical Physics

Abstract

The equilibrium properties of a Janus fluid made of two-face particles confined to a one-dimensional channel are revisited. The exact Gibbs free energy for a finite number of particles NN is exactly derived for both quenched and annealed realizations. It is proved that the results for both classes of systems tend in the thermodynamic limit (NN\to\infty) to a common expression recently derived (Maestre M A G and Santos A 2020 J Stat Mech 063217). The theoretical finite-size results are particularized to the Kern--Frenkel model and confirmed by Monte Carlo simulations for quenched and (both biased and unbiased) annealed systems.

Keywords

Cite

@article{arxiv.2107.13883,
  title  = {Finite-size effects and thermodynamic limit in one-dimensional Janus fluids},
  author = {R. Fantoni and M. A. G. Maestre and A. Santos},
  journal= {arXiv preprint arXiv:2107.13883},
  year   = {2021}
}

Comments

23 one-column pages, 6 figures; v2: minor changes

R2 v1 2026-06-24T04:38:23.268Z