Finite-size effects and thermodynamic limit in one-dimensional Janus fluids
Statistical Mechanics
2021-10-29 v2 Soft Condensed Matter
Chemical Physics
Abstract
The equilibrium properties of a Janus fluid made of two-face particles confined to a one-dimensional channel are revisited. The exact Gibbs free energy for a finite number of particles is exactly derived for both quenched and annealed realizations. It is proved that the results for both classes of systems tend in the thermodynamic limit () to a common expression recently derived (Maestre M A G and Santos A 2020 J Stat Mech 063217). The theoretical finite-size results are particularized to the Kern--Frenkel model and confirmed by Monte Carlo simulations for quenched and (both biased and unbiased) annealed systems.
Cite
@article{arxiv.2107.13883,
title = {Finite-size effects and thermodynamic limit in one-dimensional Janus fluids},
author = {R. Fantoni and M. A. G. Maestre and A. Santos},
journal= {arXiv preprint arXiv:2107.13883},
year = {2021}
}
Comments
23 one-column pages, 6 figures; v2: minor changes