Exciton-phonon coupling limits the homogeneous emission linewidth of nanocrystals. Hence, a full understanding of it is crucial. In this work, we statistically investigate exciton-phonon coupling by performing single-particle spectroscopy on Zn1−xCdxSe/CdS dot-in-rod nanocrystals at cryogenic temperatures (T≈10K). In situ cation exchange enables us to analyze different band alignments and thereby different charge-carrier distributions. We find that the relative intensities of the longitudinal optical S- and Se-type phonon replicas correlate with the charge-carrier distribution. Our experimental findings are complemented with quantum mechanical calculations within the effective mass approximation that hint at the relevance of surface charges.
@article{arxiv.2404.11516,
title = {Exciton-Phonon Coupling in Single Band-Gap Engineered ZnCdSe-Dot/CdS-Rod Nanocrystals},
author = {Florian Johst and Jannik Rebmann and Hans Werners and Lars Klemeyer and Jagadesh Kopula Kesavan and Dorota Koziej and Christian Strelow and Gabriel Bester and Alf Mews and Tobias Kipp},
journal= {arXiv preprint arXiv:2404.11516},
year = {2024}
}