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Electric-field-controlled cold dipolar collisions between trapped CH$_3$F molecules

Atomic Physics 2022-05-18 v1 Chemical Physics Quantum Physics

Abstract

Reaching high densities is a key step towards cold-collision experiments with polyatomic molecules. We use a cryofuge to load up to 2×107\times10^7 CH3_3F molecules into a box-like electric trap, achieving densities up to 107^7/cm3^3 at temperatures around 350 mK where the elastic dipolar cross-section exceeds 7×\times1012^{-12}cm2^2. We measure inelastic rate constants below 4×\times108^{-8}cm3^3/s and control these by tuning a homogeneous electric field that covers a large fraction of the trap volume. Comparison to ab-initio calculations gives excellent agreement with dipolar relaxation. Our techniques and findings are generic and immediately relevant for other cold-molecule collision experiments.

Keywords

Cite

@article{arxiv.2204.12339,
  title  = {Electric-field-controlled cold dipolar collisions between trapped CH$_3$F molecules},
  author = {M. Koller and F. Jung and J. Phrompao and M. Zeppenfeld and I. M. Rabey and G. Rempe},
  journal= {arXiv preprint arXiv:2204.12339},
  year   = {2022}
}

Comments

To be published in Physical Review Letters: https://journals.aps.org/prl/accepted/e5070Y42Cf013066f8871d5761f80f99fa8136ff5