In this work, we present a theory to address conflicting experimental claims regarding the charge density wave (CDW) state in TiSe2, including whether there is a single or multiple CDW transitions and whether threefold rotation symmetry (C3) is broken. Using a continuum k⋅p model coupled to the CDW order parameter, we show how commonplace conduction band doping induces a nematic transition from a C3-symmetric 3Q CDW to a C3-breaking 3Q CDW, which is favored by the large ellipticity of the conduction bands of TiSe2. We also find that a 1Q stripe CDW is generically stabilized for sufficiently high electron doping. We then show how both stripe and nematic CDW states emerge self-consistently from a minimal interacting tight-binding model, for both positive and negative initial gaps. Our theory provides a new scenario in which, as temperature is lowered, a second C3-breaking transition may occur or not depending on the doping level, potentially explaining the experimental variability. These predictions can be further verified with a variety of probes including transport, photoemission and tunneling.
@article{arxiv.2308.15541,
title = {Doping-induced nematic and stripe orders within the charge density wave state of TiSe$_2$},
author = {Daniel Muñoz-Segovia and Jörn W. F. Venderbos and Adolfo G. Grushin and Fernando de Juan},
journal= {arXiv preprint arXiv:2308.15541},
year = {2025}
}
Comments
7+9 pages, 4+2 figures. [Editors' suggestion in PRB]