English

Current with "wrong" sign and phase transitions

Mathematical Physics 2019-05-22 v1 math.MP

Abstract

We prove that under certain conditions, phase separation is enough to sustain a regime in which current flows along the concentration gradient, a phenomenon which is known in the literature as \textit{uphill diffusion}. The model we consider here is a version of that proposed in [G. B. Giacomin, J. L. Lebowitz, Phase segregation dynamics in particle system with long range interactions, Journal of Statistical Physics 87(1) (1997): 37-61], which is the continuous mesoscopic limit of a 1d1d discrete Ising chain with a Kac potential. The magnetization profile lies in the interval [ε1,ε1]\left[-\varepsilon^{-1},\varepsilon^{-1}\right], ε>0\varepsilon>0, staying in contact at the boundaries with infinite reservoirs of fixed magnetization ±μ\pm\mu, μ(m(β),1)\mu\in(m^*\left(\beta\right),1), where m(β)=11/βm^*\left(\beta\right)=\sqrt{1-1/\beta}, β>1\beta>1 representing the inverse temperature. At last, an external field of Heaviside-type of intensity κ>0\kappa>0 is introduced. According to the axiomatic non-equilibrium theory, we derive from the mesoscopic free energy functional the corresponding stationary equation and prove the existence of a solution, which is antisymmetric with respect to the origin and discontinuous in x=0x=0, provided ε\varepsilon is small enough. When μ\mu is metastable, the current is positive and bounded from below by a positive constant independent of κ\kappa, this meaning that both phase transition as well as external field contributes to uphill diffusion, which is a regime that actually survives when the external bias is removed.

Keywords

Cite

@article{arxiv.1810.04639,
  title  = {Current with "wrong" sign and phase transitions},
  author = {Roberto Boccagna},
  journal= {arXiv preprint arXiv:1810.04639},
  year   = {2019}
}
R2 v1 2026-06-23T04:35:10.747Z