English

Current Crowding in a High-Efficiency Black Phosphorus Light-Emitting Diode Using a Reflective Back Contact

Applied Physics 2025-06-12 v1 Optics

Abstract

We demonstrate a high-performance mid-infrared (MIR) light-emitting diode (LED) based on a black phosphorus (b-P)/n-MoS2_2 heterojunction. A gold back contact combined with a rhenium-doped n-type MoS2_2 layer is used to enhance light extraction. The device shows a MIR peak external quantum efficiency (EQE) of (1.6 ±\pm 0.2) % at room temperature and a record (7.0 ±\pm 0.5) % EQE at 77 K, with a maximum radiant power density of (108 ±\pm 8) W/cm2. Finite-element simulations highlight the importance of phonon-assisted band-to-band tunneling under reverse bias and the influence of carrier velocity saturation under forward bias. The simulations also reveal that the high ideality factors extracted from the current-voltage characteristic are due to current crowding at the heterojunction and a consequence of the device geometry. These findings establish a new high-performance b-P LED architecture and provide crucial insights into the physics of MIR sources based on 2D materials.

Keywords

Cite

@article{arxiv.2506.09835,
  title  = {Current Crowding in a High-Efficiency Black Phosphorus Light-Emitting Diode Using a Reflective Back Contact},
  author = {Julien Brodeur and Éloïse Rahier and Mathieu Chartray-Pronovost and Étienne Robert and Oussama Moutanabbir and Stéphane Kéna-Cohen},
  journal= {arXiv preprint arXiv:2506.09835},
  year   = {2025}
}
R2 v1 2026-07-01T03:11:29.037Z