We study the ground state properties, the electronic excitations and lattice dynamics in spin-liquid candidate TbInO3. By employing polarization resolved Raman spectroscopy we define the inter- and intra-multiplet excitations, and establish the low-energy crystal-field (CF) level scheme. In particular, we demonstrate that the ground state of the Tb3+ ions is a non-Kramers doublet, and relate the enhanced linewidth of the CF modes to the magnetic fluctuations near the spin-liquid ground state. We identify all 38 allowed Raman-active phonon modes at low temperature. Moreover, we observe hybrid vibronic excitations involving coupled CF and low-lying phonon modes, suggesting strong spin-lattice dynamics. We develop a model for vibronic states and obtain the parameters of the bare responses and coupling strength. We further demonstrate that the obtained CF level scheme is consistent with specific heat data.
@article{arxiv.2105.12656,
title = {Crystal-field excitations and vibronic modes in triangular-lattice spin-liquid candidate TbInO$_3$},
author = {Mai Ye and Xianghan Xu and Xiangyue Wang and Jaewook Kim and Sang-Wook Cheong and Girsh Blumberg},
journal= {arXiv preprint arXiv:2105.12656},
year = {2021}
}