Kim and co-authors in a recent article reported a phosphor Na3-2xSc2(PO4)3:xEu2+ (NSPO:xEu2+) that did not exhibit thermal quenching (TQ) even up to 200 degree Celsius. The authors suggested that zero-TQ originates from the compensation of emission losses due to the polymorphic nature of the host and the energy transfer from traps consisting of electron-hole pairs to the 5d-band of Eu2+, leading to radiative recombination. The temperature-dependent excitation and emission spectra seemingly supported the authors' assertion. However, a close inspection of the CIE chromaticity coordinates and correlated color temperature (CCT) the WLED prototype fabricated using NSPO:0.03Eu2+ , La3Si6N11:Ce3+ and (SrCa)AlSiN3:Eu2+ as a blue, yellow and red-emitting component respectively (abbreviated as WLED device hereafter) under operating currents of 100-1000 mA alongside a series of optical characterization results of NSPO:xEu2+ indicates that the so-called zero-TQ should not be the case. There were some questionable points in optical characterization of the phosphors. The observed increase in intensity upon elevating temperature in the temperature-dependent excitation and emission spectra was likely a pitfall caused by optical path length variation of the spectrofluorimeter induced by lattice thermal expansion and phase transitions.
Cite
@article{arxiv.1904.08769,
title = {Comment on a zero-thermal-quenching phosphor},
author = {Shirun Yan},
journal= {arXiv preprint arXiv:1904.08769},
year = {2019}
}