Graphene has attracted a lot of research interests due to its exotic properties and a wide spectrum of potential applications. Chemical vapor deposition (CVD) from gaseous hydrocarbon sources has shown great promises for large-scale graphene growth. However, high growth temperature, typically 1000{\deg}C, is required for such growth. Here we demonstrate a revised CVD route to grow graphene on Cu foils at low temperature, adopting solid and liquid hydrocarbon feedstocks. For solid PMMA and polystyrene precursors, centimeter-scale monolayer graphene films are synthesized at a growth temperature down to 400{\deg}C. When benzene is used as the hydrocarbon source, monolayer graphene flakes with excellent quality are achieved at a growth temperature as low as 300{\deg}C. The successful low-temperature growth can be qualitatively understood from the first principles calculations. Our work might pave a way to undemanding route for economical and convenient graphene growth.
@article{arxiv.1101.5664,
title = {Chemical Vapor Deposition Growth of Graphene using Other Hydrocarbon Sources},
author = {Zhancheng Li and Ping Wu and Chenxi Wang and Xiaodong Fan and Wenhua Zhang and Xiaofang Zhai and Changgan Zeng and Zhenyu Li and Jinlong Yang and J. G. Hou},
journal= {arXiv preprint arXiv:1101.5664},
year = {2011}
}