This study investigates photon entanglement generated from para-positronium decay by analyzing azimuthal correlations after the double Compton scattering with stationary electrons. We introduce a normalized correlation observable O1=cos(2ϕ1−2ϕ2)/C1 to witness entanglement. In the absence of decoherence, ⟨O1⟩=−1, corresponding to a maximally entangled Bell state. With decoherence parameterized by ρ, the expectation becomes −(1−ρ), allowing direct experimental quantification of coherence loss. A prior symmetry analysis of the Compton scattering process within the quantum field theory (QFT) is provided, which establishes the mirror-symmetric nature of the single-photon angular distribution. We further examine a local hidden-variable theory (LHVT) under the angular-momentum conservation. Imposing the mirror symmetry with respect to the plane defined by the photon spin and momentum leads to a non-negative LHVT prediction for ⟨sin2θ1sin2θ2cos(2ϕ1−2ϕ2)⟩, contradicting the negative QFT prediction value for any ρ<1. Thus, mirror symmetry serves as a novel criterion to exclude LHVT descriptions of the entangled state, whereas without preserving this symmetry, LHVTs can reproduce the correlations.