English

C-type shock modelling -- the effect of new H$_2$-H collisional rate coefficients

Astrophysics of Galaxies 2019-09-18 v1

Abstract

We consider collisional excitation of H2_2 molecules in C-type shocks propagating in dense molecular clouds. New data on collisional rate coefficients for (de-)excitation of H2_2 molecule in collisions with H atoms and new H2_2 dissociation rates are used. The new H2_2-H collisional data are state of the art and are based on the most accurate H3_3 potential energy surface. We re-examine the excitation of rotational levels of H2_2 molecule, the para-to-ortho-H2_2 conversion, and H2_2 dissociation by H2_2-H collisions. At cosmic ray ionization rates ζ1016\zeta \geq 10^{-16} s1^{-1} and at moderate shock speeds, the H/H2_2 ratio at the shock front is mainly determined by the cosmic ray ionization rate. The H2_2-H collisions play the main role in the para-to-ortho-H2_2 conversion and, at ζ1015\zeta \geq 10^{-15} s1^{-1}, in the excitation of vibrationally excited states of H2_2 molecule in the shock. The H2_2 ortho-to-para ratio (OPR) of the shocked gas and column densities of rotational levels of vibrationally excited states of H2_2 are found to depend strongly on the cosmic ray ionization rate. We discuss the applicability of the presented results to interpretation of observations of H2_2 emission in supernova remnants.

Keywords

Cite

@article{arxiv.1909.07738,
  title  = {C-type shock modelling -- the effect of new H$_2$-H collisional rate coefficients},
  author = {A. V. Nesterenok and D. Bossion and Y. Scribano and F. Lique},
  journal= {arXiv preprint arXiv:1909.07738},
  year   = {2019}
}

Comments

10 pages, 4 figures, accepted for publication in MNRAS