English

Bound Pairs: Direct Evidence for Long-range Attraction between Like-Charged Colloids

Soft Condensed Matter 2009-11-13 v1 Statistical Mechanics

Abstract

We report observations of stable bound pairs in very dilute deionized aqueous suspensions of highly charged polystyrene colloidal particles, with monovalent counterions, using a confocal laser scanning microscope. Through an analysis of several thousands of time series of confocal images recorded deep inside the bulk suspension, we find that the measured pair-potential, U(r) has a long-range attractive component with well depths larger than the thermal energy. These observations provide a direct and unequivocal evidence for the existence of long-range attraction in U(r) of like-charged colloidal particles.

Keywords

Cite

@article{arxiv.0711.2883,
  title  = {Bound Pairs: Direct Evidence for Long-range Attraction between Like-Charged Colloids},
  author = {B. V. R. Tata and P. S. Mohanty and M. C. Valsakumar},
  journal= {arXiv preprint arXiv:0711.2883},
  year   = {2009}
}

Comments

8 pages, 4 figures, submitted to Phys. Rev. Lett

R2 v1 2026-06-21T09:44:45.119Z