Asymptotic energy of graphs

The energy of a simple graph $G$ arising in chemical physics, denoted by $\mathcal E(G)$, is defined as the sum of the absolute values of eigenvalues of $G$. We consider the asymptotic energy per vertex (say asymptotic energy) for lattice systems. In general for a type of lattice in statistical physics, to compute the asymptotic energy with toroidal, cylindrical, Mobius-band, Klein-bottle, and free boundary conditions are different tasks with different hardness. In this paper, we show that if $\{G_n\}$ is a sequence of finite simple graphs with bounded average degree and $\{G_n'\}$ a sequence of spanning subgraphs of $\{G_n\}$ such that almost all vertices of $G_n$ and $G_n'$ have the same degrees, then $G_n$ and $G_n'$ have the same asymptotic energy. Thus, for each type of lattices with toroidal, cylindrical, Mobius-band, Klein-bottle, and free boundary conditions, we have the same asymptotic energy. As applications, we obtain the asymptotic formulae of energies per vertex of the triangular, $3^3.4^2$, and hexagonal lattices with toroidal, cylindrical, Mobius-band, Klein-bottle, and free boundary conditions simultaneously.