α-YbAlB4 is the locally isostructural polymorph of β-YbAlB4, the first example of an Yb-based heavy fermion superconductor which exhibits pronounced non-Fermi-liquid behavior above Tc. Interestingly, both α-YbAlB4 and β-YbAlB4 have strongly intermediate valence. Our single crystal study of the specific heat, magnetization and resistivity has confirmed the Fermi liquid ground state of α-YbAlB4 ~in contrast with the quantum criticality observed in β-YbAlB4. Both systems exhibit Kondo lattice behavior with the characteristic temperature scale T∗∼ 8 K in addition to a valence fluctuation scale ∼200 K. Below T∗, α-YbAlB4 a heavy Fermi liquid state with an electronic specific heat coefficient γ∼ 130 mJ/mol K2 and a large Wilson ratio more than 7, which indicates ferromagnetic correlation between Yb moments. A large anisotropy in the resistivity suggests that the hybridization between 4f and conduction electrons is much stronger in the ab-plane than along the c-axis. The strongly anisotropic hybridization as well as the large Wilson ratio is the key to understand the unusual Kondo lattice behavior and heavy fermion formation in mixed valent compounds.
@article{arxiv.1105.2144,
title = {Anisotropic heavy Fermi-liquid formation in the valence fluctuating $\alpha$-YbAlB$_4$},
author = {Yosuke Matsumoto and K. Kuga and T. Tomita and Y. Karaki and S. Nakatsuji},
journal= {arXiv preprint arXiv:1105.2144},
year = {2015}
}