English

A variational formula for the free energy of the partially directed polymer collapse

Probability 2015-06-12 v1

Abstract

Long linear polymers in dilute solutions are known to undergo a collapse transition from a random coil (expand itself) to a compact ball (fold itself up) when the temperature is lowered, or the solvent quality deteriorates. A natural model for this phenomenon is a 1+1 dimensional self-interacting and partially directed self-avoiding walk. In this paper, we develop a new method to study the partition function of this model, from which we derive a variational formula for the free energy. This variational formula allows us to prove the existence of the collapse transition and to identify the critical temperature in a simple way. We also prove that the order of the collapse transition is 3/2.

Keywords

Cite

@article{arxiv.1211.0925,
  title  = {A variational formula for the free energy of the partially directed polymer collapse},
  author = {Gia Bao Nguyen and Nicolas Petrelis},
  journal= {arXiv preprint arXiv:1211.0925},
  year   = {2015}
}

Comments

18 pages, 5 figures