A variational formula for the free energy of the partially directed polymer collapse
Probability
2015-06-12 v1
Abstract
Long linear polymers in dilute solutions are known to undergo a collapse transition from a random coil (expand itself) to a compact ball (fold itself up) when the temperature is lowered, or the solvent quality deteriorates. A natural model for this phenomenon is a 1+1 dimensional self-interacting and partially directed self-avoiding walk. In this paper, we develop a new method to study the partition function of this model, from which we derive a variational formula for the free energy. This variational formula allows us to prove the existence of the collapse transition and to identify the critical temperature in a simple way. We also prove that the order of the collapse transition is 3/2.
Keywords
Cite
@article{arxiv.1211.0925,
title = {A variational formula for the free energy of the partially directed polymer collapse},
author = {Gia Bao Nguyen and Nicolas Petrelis},
journal= {arXiv preprint arXiv:1211.0925},
year = {2015}
}
Comments
18 pages, 5 figures