English

A study of uranium-based multilayers: I. Fabrication and structural characterisation

Materials Science 2007-05-23 v1 Other Condensed Matter

Abstract

This paper addresses the structural characterisation of a series of U/Fe, U/Co and U/Gd multilayers. X-ray reflectivity has been employed to investigate the layer thickness and roughness parameters along the growth direction and high-angle diffraction measurements have been used to determine the crystal structure and orientation of the layers. For the case of uranium/transition metal systems, the interfaces are diffuse and the transition metals are present in a polycrystalline form of their common bulk phases with a preferred orientation along the closest packed planes; Fe, bcc (110) and Co, hcp (001), respectively. The uranium is present in a poorly crystalline orthorhombic, alpha-U state. In contrast, the U/Gd multilayers have sharp interfaces with negligible intermixing of atomic species, and have a roughness, which is strongly dependent on the gadolinium layer thickness. Diffraction spectra indicate a high degree of crystallinity in both U and Gd layers with intensities consistent with the growth of a novel hcp U phase, stabilised by the hcp gadolinium layers.

Keywords

Cite

@article{arxiv.0704.3947,
  title  = {A study of uranium-based multilayers: I. Fabrication and structural characterisation},
  author = {R Springell and S W Zochowski and R C C Ward and M R Wells and S D Brown and L Bouchenoire and F Wilhelm and S Langridge and W G Stirling and G H Lander},
  journal= {arXiv preprint arXiv:0704.3947},
  year   = {2007}
}
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