A Corpuscular Picture of Electrons in Chemical Bond
Chemical Physics
2016-04-06 v1
Abstract
We introduce a theory of chemical bond with a corpuscular picture of electrons. It employs a minimal set of localized electron wave packets with 'floating and breathing' degrees of freedom and the spin-coupling of non-orthogonal valence-bond theory. It accurately describes chemical bonds in ground and excited states of spin singlet and triplet, in a distinct manner from conventional theories, indicating potential for establishing a dynamical theory of electrons in chemical bonds.
Keywords
Cite
@article{arxiv.1511.05331,
title = {A Corpuscular Picture of Electrons in Chemical Bond},
author = {Koji Ando},
journal= {arXiv preprint arXiv:1511.05331},
year = {2016}
}
Comments
4 pages, 4 figures