English

3$d$ - 4$d$ hybridization anomaly in Ni$_x$Pd$_{1-x}$ alloys at quantum critical point

Strongly Correlated Electrons 2017-05-24 v1

Abstract

FirstprinciplesFirst-principles density functional theory computations of electronic structure and local magnetic properties of the non-fluctuating ground state of Nix_xPd1x_{1-x} alloy system around its quantum critical point xc=0.026x_c = 0.026 have been performed. The density of states at the Fermi energy and certain other parameters characterizing the Ni 3dd - Pd 4dd hybridization apparently follow power-laws with xx similar to that obeyed by the reported ferromagnetic to paramagnetic transition temperature. The width of Pd 4d4d density of states (DOS) and centroid of Ni 3dd DOS show peak-like anomalies in the neighbourhood of xcx_c, and so indicate a possible scenario of the existence of a definite relation between the orbital hybridization and the emergence of quantum fluctuations in the system.

Keywords

Cite

@article{arxiv.1703.09967,
  title  = {3$d$ - 4$d$ hybridization anomaly in Ni$_x$Pd$_{1-x}$ alloys at quantum critical point},
  author = {P. Swain and Sanjeev K. Srivastava and Suneel K. Srivastava},
  journal= {arXiv preprint arXiv:1703.09967},
  year   = {2017}
}