The He2 - OCS complex: comparison between theory and experiment
Atomic and Molecular Clusters
2018-03-14 v1
Abstract
OCS is an ideal probe for quantum solvation effects in cold helium clusters. He2-OCS is the "second step" in going from a single OCS molecule to a large doped superfluid helium cluster. Here assignment of the spectrum of He2-OCS is significantly extended to higher values of J, K, and vt (the low frequency torsional vibration). The observation of a new infrared band, OCS nu1 + nu3, taken together with the known nu1 band, enables assignments to be verified by comparing ground state combination differences. Relatively straightforward scaling of previously calculated theoretical energy levels gives a remarkably good fit to experiment
Cite
@article{arxiv.1710.11570,
title = {The He2 - OCS complex: comparison between theory and experiment},
author = {J. Norooz Oliaee and N. Moazzen-Ahmadi and A. R. W. McKellar and Xiao-Gang Wang and Tucker Carrington},
journal= {arXiv preprint arXiv:1710.11570},
year = {2018}
}
Comments
34 pages, 2 figures