English

Symplectic algorithm for constant-pressure molecular dynamics using a Nose-Poincare thermostat

Chemical Physics 2009-10-31 v1

Abstract

We present a new algorithm for isothermal-isobaric molecular-dynamics simulation. The method uses an extended Hamiltonian with an Andersen piston combined with the Nos'e-Poincar'e thermostat, recently developed by Bond, Leimkuhler and Laird [J. Comp. Phys., 151, (1999)]. This Nos'e-Poincar'e-Andersen (NPA) formulation has advantages over the Nos'e-Hoover-Andersen approach in that the NPA is Hamiltonian and can take advantage of symplectic integration schemes, which lead to enhanced stability for long-time simulations. The equations of motion are integrated using a Generalized Leapfrog Algorithm and the method is easy to implement, symplectic, explicit and time reversible. To demonstrate the stability of the method we show results for test simulations using a model for aluminum.

Keywords

Cite

@article{arxiv.physics/9903009,
  title  = {Symplectic algorithm for constant-pressure molecular dynamics using a Nose-Poincare thermostat},
  author = {Jess B. Sturgeon and Brian B. Laird},
  journal= {arXiv preprint arXiv:physics/9903009},
  year   = {2009}
}

Comments

7 pages

R2 v1 2026-07-22T19:18:50.379Z