Speed-gradient principle for nonstationary processes in thermodynamics
General Physics
2007-05-23 v1
Abstract
The speed-gradient variational principle (SG-principle) is formulated and applied to thermodynamical systems. It is shown that Prigogine's principle of minimum entropy production and Onsager's symmetry relations can be interpreted in terms of the SG-principle and, therefore, are equivalent to each other. In both cases entropy of the system plays a role of the goal functional. The speed-gradient formulation of thermodynamic principles provide their extended versions, describing transient dynamics of nonstationary systems far from equilibrium. As an example a model of transient (relaxation) dynamics for maximum entropy principle is derived.
Keywords
Cite
@article{arxiv.physics/0701312,
title = {Speed-gradient principle for nonstationary processes in thermodynamics},
author = {Alexander L. Fradkov},
journal= {arXiv preprint arXiv:physics/0701312},
year = {2007}
}
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5 pages