English

Reentrant disorder-disorder transitions in generalized multicomponent Widom-Rowlinson models

Statistical Mechanics 2016-01-05 v1

Abstract

In the lattice version of the multicomponent Widom-Rowlinson (WR) model, each site can be either empty or singly occupied by one of MM different particles, all species having the same fugacity zz. The only nonzero interaction potential is a nearest-neighbor hard-core exclusion between unlike particles. For M<M0M<M_0 with some minimum M0M_0 dependent on the lattice structure, as zz increases from 0 to \infty there is a direct transition from the disordered (gas) phase to a demixed (liquid) phase with one majority component at z>zd(M)z>z_d(M). If MM0M\ge M_0, there is an intermediate ordered "crystal phase" (composed of two nonequivalent even and odd sublattices) for zz lying between zc(M)z_c(M) and zd(M)z_d(M) which is driven by entropy. We generalize the multicomponent WR model by replacing the hard-core exclusion between unlike particles by more realistic large (but finite) repulsion. The model is solved exactly on the Bethe lattice with an arbitrary coordination number. The numerical calculations, based on the corner transfer matrix renormalization group, are performed for the two-dimensional square lattice. The results for M=4M=4 indicate that the second-order phase transitions from the disordered gas to the demixed phase become of first order, for an arbitrarily large finite repulsion. The results for MM0M\ge M_0 show that, as the repulsion weakens, the region of crystal phase diminishes itself. For weak enough repulsions, the direct transition between the crystal and demixed phases changes into a separate pair of crystal-gas and gas-demixed transitions; this is an example of a disorder-disorder reentrant transition via an ordered crystal phase. If the repulsion between unlike species is too weak, the crystal phase disappears from the phase diagram. It is shown that the generalized WR model belongs to the Ising universality class.

Keywords

Cite

@article{arxiv.1601.00515,
  title  = {Reentrant disorder-disorder transitions in generalized multicomponent Widom-Rowlinson models},
  author = {Roman Krčmár and Ladislav Šamaj},
  journal= {arXiv preprint arXiv:1601.00515},
  year   = {2016}
}

Comments

9 pages, 10 figures

R2 v1 2026-06-22T12:22:30.432Z