Orientation selection in lamellar phases by oscillatory shears
Soft Condensed Matter
2009-11-11 v1
Abstract
In order to address the selection mechanism that is responsible for the unique lamellar orientation observed in block copolymers under oscillatory shears, we use a constitutive law for the dissipative part of the stress tensor that respects the uniaxial symmetry of a lamellar phase. An interface separating two domains oriented parallel and perpendicular to the shear is shown to be hydrodynamically unstable, a situation analogous to the thin layer instability of stratified fluids under shear. The resulting secondary flows break the degeneracy between parallel and perpendicular lamellar orientation, leading to a preferred perpendicular orientation in certain ranges of parameters of the polymer and of the shear.
Cite
@article{arxiv.cond-mat/0601355,
title = {Orientation selection in lamellar phases by oscillatory shears},
author = {Zhi-Feng Huang and Jorge Vinals},
journal= {arXiv preprint arXiv:cond-mat/0601355},
year = {2009}
}
Comments
4 pages, 3 figures