Orbital Collapse in Exotic Atoms and Its Effect on Dynamics

We study the energy structures of muonic Ar atoms and find the muon orbital collapses at a critical angular momentum $l_c$ using density-functional theory (DFT). The $l_c$ may provide an upper limit for the muon-captured states in muon-Ar collisions. We confirm the existence of this upper limit by calculating the state-specified capture probability using the time-dependent Schr\"odinger equation (TDSE) and a classical trajectory Monte Carlo (CTMC) methods with the single-active-particle approximation. Modifying the mapping between the classical binding energy and the principal quantum number led to a reasonable agreement in the state-specified muon capture probabilities obtained by the TDSE and CTMC methods. We also propose a simple method to estimate $l_c$ for exotic noble atoms from atomic model potentials. The estimated values agree with those calculated by DFT.