Optical activity tensor for radiating atomic and molecular systems
Abstract
The optical activity tensor (OAT) is explicitly derived. It is shown that to evaluate a large number of effects related to optical activity of some atomic/molecular system at arbitrary frequency of the incident light, one needs to know only four optical activity tensors which have twelve irreducible (tensor) components. An additional amplification factor contains one tensor of light scattering with three irreducible components. The explicit dependence of all irreducible components of OAT upon and some molecular parameters is derived and discussed. We apply OAT to explain the dispersion of optical rotation in dilute solutions of organic molecules. This study opens a new avenue in application of methods of modern Quantum Electrodynamics to the optical activity.
Cite
@article{arxiv.1009.6016,
title = {Optical activity tensor for radiating atomic and molecular systems},
author = {Alexei M. Frolov and David M. Wardlaw},
journal= {arXiv preprint arXiv:1009.6016},
year = {2010}
}