On the formation/dissolution of equilibrium droplets
Abstract
We consider liquid-vapor systems in finite volume at parameter values corresponding to phase coexistence and study droplet formation due to a fixed excess of particles above the ambient gas density. We identify a dimensionless parameter and a \textrm{universal} value , and show that a droplet of the dense phase occurs whenever , while, for , the excess is entirely absorbed into the gaseous background. When the droplet first forms, it comprises a non-trivial, \textrm{universal} fraction of excess particles. Similar reasoning applies to generic two-phase systems at phase coexistence including solid/gas--where the ``droplet'' is crystalline--and polymorphic systems. A sketch of a rigorous proof for the 2D Ising lattice gas is presented; generalizations are discussed heuristically.
Cite
@article{arxiv.math-ph/0207012,
title = {On the formation/dissolution of equilibrium droplets},
author = {Marek Biskup and Lincoln Chayes and Roman Kotecky},
journal= {arXiv preprint arXiv:math-ph/0207012},
year = {2009}
}
Comments
An announcement of a forthcoming rigorous work on the 2D Ising model; to appear in Europhys. Lett