English

Non-stochastic matrix Schr\"odinger equation for open systems

Chemical Physics 2015-07-20 v2

Abstract

We propose an extension of the Schr\"odinger equation for a quantum system interacting with environment. This equation describes dynamics of auxiliary wave-functions m\mathbf{m}, from which the system density matrix can be reconstructed as ρ^=mm\hat{\rho} = \mathbf{m} \mathbf{m}^\dagger. We formulate a compatibility condition, which ensures that the reconstructed density satisfies a given quantum master equation for the system density. The resulting non-stochastic evolution equation preserves positive-definiteness of the system density and is applicable to both Markovian and non-Markovian system-bath treatments. Our formalism also resolves a long-standing problem of energy non-conservation in the time-dependent variational principle applied to mixed states of closed systems.

Keywords

Cite

@article{arxiv.1408.6624,
  title  = {Non-stochastic matrix Schr\"odinger equation for open systems},
  author = {Loïc Joubert-Doriol and Ilya G. Ryabinkin and Artur F. Izmaylov},
  journal= {arXiv preprint arXiv:1408.6624},
  year   = {2015}
}

Comments

5 pages, 2 figures

R2 v1 2026-06-22T05:42:25.789Z