Non-stochastic matrix Schr\"odinger equation for open systems
Chemical Physics
2015-07-20 v2
Abstract
We propose an extension of the Schr\"odinger equation for a quantum system interacting with environment. This equation describes dynamics of auxiliary wave-functions , from which the system density matrix can be reconstructed as . We formulate a compatibility condition, which ensures that the reconstructed density satisfies a given quantum master equation for the system density. The resulting non-stochastic evolution equation preserves positive-definiteness of the system density and is applicable to both Markovian and non-Markovian system-bath treatments. Our formalism also resolves a long-standing problem of energy non-conservation in the time-dependent variational principle applied to mixed states of closed systems.
Cite
@article{arxiv.1408.6624,
title = {Non-stochastic matrix Schr\"odinger equation for open systems},
author = {Loïc Joubert-Doriol and Ilya G. Ryabinkin and Artur F. Izmaylov},
journal= {arXiv preprint arXiv:1408.6624},
year = {2015}
}
Comments
5 pages, 2 figures