English

Migration and separation of polymers in non-uniform active baths

Soft Condensed Matter 2024-03-12 v1 Statistical Mechanics

Abstract

Polymer-like structures are ubiquitous in nature and synthetic materials. Their configurational and migration properties are often affected by crowded environments leading to non-thermal fluctuations. Here, we study an ideal Rouse chain in contact with a non-homogeneous active bath, characterized by the presence of active self-propelled agents which exert time-correlated forces on the chain. By means of a coarse-graining procedure, we derive an effective evolution for the center of mass of the chain and show its tendency to migrate towards and preferentially localize in regions of high/low bath activity depending on the model parameters. In particular, we demonstrate that an active bath with non-uniform activity can be used to separate efficiently polymeric species with different lengths and/or connectivity.

Keywords

Cite

@article{arxiv.2403.05914,
  title  = {Migration and separation of polymers in non-uniform active baths},
  author = {Pietro Luigi Muzzeddu and Andrea Gambassi and Jens-Uwe Sommer and Abhinav Sharma},
  journal= {arXiv preprint arXiv:2403.05914},
  year   = {2024}
}

Comments

10 pages, 4 figures

R2 v1 2026-06-28T15:14:30.737Z