As typical solid-state electrolytes (SSEs), {Na}1+x{Zr}2{Si}x{P}3−x{O}12 NASICONs provide an ideal platform for solid-state batteries (SSBs) that display higher safety and accommodate higher energy densities. The critical points for achieving SSBs with higher efficiencies are to improve essentially the ionic conductivity and to reduce largely the interfacial resistance between SSEs and cathode materials, which would necessitate extremely high level of craftsmanship and high-pressure equipment. An alternative to higher-performance and lower-cost SSBs is additive manufacturing. Here, we report on an effective additive, MgF2, which was used in synthesizing NASICONs, resulting in SSEs with fewer defects and higher performance. With an addition of mere 1 wt% MgF2 additive, the total room-temperature ionic conductivity of the NASICON electrolyte reaches up to 2.03 mS cm−1, improved up to ∼ 181.3%, with an activation energy of 0.277 eV. Meanwhile, the stability of the Na plating/stripping behavior in symmetric cells increases from 236 to 654 h. We tried to reveal the microscopic origins of the higher ionic conductivity of MgF2-doped NASICONs by comprehensive in-house characterizations. Our study discovers a novel MgF2 additive and provides an efficient way to prepare higher-performance SSEs, making it possible to fabricate lower-cost SSBs in industries.
Cite
@article{arxiv.2302.07264,
title = {MgF$_2$ as an effective additive for improving ionic conductivity of ceramic solid electrolytes},
author = {Pengfei Zhou and Kaitong Sun and Shunping Ji and Zirui Zhao and Ying Fu and Junchao Xia and Si Wu and Yinghao Zhu and Kwun Nam Hui and Hai-Feng Li},
journal= {arXiv preprint arXiv:2302.07264},
year = {2023}
}