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Magnetically Tunable Chirality in 2D Liquid Crystalline WS2 Nanocomposites

Materials Science 2018-04-16 v1

Abstract

The first observation of tungsten disulfide liquid crystalline nanocomposites in dispersions of liquid phase-exfoliated flakes is demonstrated in a range of organic solvents. The nanocomposites demonstrate significant birefringence and reconfigurable optical chirality as observed in the linear and circular dichroism measurements respectively. Under an applied magnetic field of +/-1.5T the chirality can be switched ON/OFF, while the wavelength range for switching can be tuned from large to narrow range by the proper selection of the host solvent. In combination with photoluminescence capabilities of WS2, this opens a pathway to a wide variety of applications, such as deposition of highly uniform films over large areas for photovoltaic devices, as shown here.

Keywords

Cite

@article{arxiv.1804.04745,
  title  = {Magnetically Tunable Chirality in 2D Liquid Crystalline WS2 Nanocomposites},
  author = {Benjamin T. Hogan and Yulia Gromova and Evgeniya Kovalska and Alexander Baranov and Monica F. Craciun and Anna Baldycheva},
  journal= {arXiv preprint arXiv:1804.04745},
  year   = {2018}
}
R2 v1 2026-06-23T01:22:22.225Z