English

Long ranged stress correlations in the hard sphere liquid

Soft Condensed Matter 2024-11-08 v1 Statistical Mechanics

Abstract

The smooth emergence of shear elasticity is an hallmark of the liquid to glass transition. In a liquid, viscous stresses arise from local structural rearrangements. In the solid, Eshelby has shown that stresses around an inclusion decay as a power law rDr^{-D}, where DD is the dimension of the system. We study glass-forming hard sphere fluids by simulation and observe the emergence of the unscreened power-law Eshelby pattern in the stress correlations of the isotropic liquid state. By a detailed tensorial analysis, we show that the fluctuating force field, viz.~the divergence of the stress field, relaxes to zero with time in all states, while the shear stress correlations develop spatial power-law structures inside regions that grow with longitudinal and transverse sound speeds; we observe the predicted exponents rDr^{-D} and rD2r^{-D-2}. In Brownian systems, shear stresses relax diffusively within these regions, with the diffusion coefficient determined by the shear modulus and the friction coefficient.

Keywords

Cite

@article{arxiv.2405.03497,
  title  = {Long ranged stress correlations in the hard sphere liquid},
  author = {Niklas Grimm and Martin von Bischopinck and Andreas Zumbusch and Matthias Fuchs},
  journal= {arXiv preprint arXiv:2405.03497},
  year   = {2024}
}

Comments

15 pages, 18 figures

R2 v1 2026-06-28T16:18:07.241Z