Local pressure for confined systems
Soft Condensed Matter
2018-02-07 v2
Abstract
We derive a general closed expression for the local pressure exerted onto the corrugated walls of a channel confining a fluid medium. When the fluid medium is at equilibrium the local pressure is a functional of the shape of the walls. It is shown that, due to the intrinsic non-local character of the interactions among the particles forming the fluid, the applicability of approximate schemes such as the concept of a surface of tension or morphometric thermodynamics is limited to wall curvatures small compared to the range of particle-particle interactions.
Cite
@article{arxiv.1711.02028,
title = {Local pressure for confined systems},
author = {Paolo Malgaretti and Markus Bier},
journal= {arXiv preprint arXiv:1711.02028},
year = {2018}
}
Comments
corrections of typos of the previous version and reorganization of part of the material in an additional appendix