Isomorphs, hidden scale invariance, and quasiuniversality
Soft Condensed Matter
2013-10-30 v3 Statistical Mechanics
Abstract
This paper first establishes an approximate scaling property of the potential-energy function of a classical liquid with good isomorphs (a Roskilde-simple liquid). This "pseudohomogeneous" property makes explicit that - and in which sense - such a system has a hidden scale invariance. The second part gives a potential-energy formulation of the quasiuniversality of monatomic Roskilde-simple liquids, which was recently rationalized in terms of the existence of a quasiuniversal single-parameter family of reduced-coordinate constant-potential-energy hypersurfaces [J. C. Dyre, Phys. Rev. E 87, 022106 (2013)]. The new formulation involves a quasiuniversal reduced-coordinate potential-energy function. A few consequences of this are discussed.
Cite
@article{arxiv.1306.4699,
title = {Isomorphs, hidden scale invariance, and quasiuniversality},
author = {Jeppe C. Dyre},
journal= {arXiv preprint arXiv:1306.4699},
year = {2013}
}