English

Is gelation a singularity or a flow induced instability?

Soft Condensed Matter 2026-01-28 v1 Adaptation and Self-Organizing Systems Applications

Abstract

Gelation in the Smoluchowski coagulation equation is commonly interpreted as a finite-time singularity marked by mass loss or moment divergence. We instead characterize gelation as a loss of dynamical stability of the Smoluchowski flow, quantified through the time-dependent spectrum of the Jacobian along the evolving aggregation dynamics. Studying homogeneous kernels K(i,j)=(ij)αK(i,j)=(ij)^{\alpha} together with the classical Smoluchowski, we show that gelation is consistently preceded by the appearance of positive real eigenvalues, indicating a loss of local dynamical stability. While non-gelling kernels exhibit only transient finite-size effects, gelling kernels display persistent spectral destabilization associated with macroscopic gel formation. Our results identify gelation as a genuine dynamical instability of the Smoluchowski flow.

Keywords

Cite

@article{arxiv.2601.18806,
  title  = {Is gelation a singularity or a flow induced instability?},
  author = {Manuel Dedola and Ludovico Cademartiri},
  journal= {arXiv preprint arXiv:2601.18806},
  year   = {2026}
}
R2 v1 2026-07-01T09:20:56.439Z