English

From sub-aging to hyper-aging in structural glasses

Soft Condensed Matter 2022-12-15 v1

Abstract

We demonstrate non-equilibrium scaling laws for the aging dynamics in glass formers that emerge from combining a recent application of Onsager's theory of irreversible processes with the equilibrium scaling laws of glassy dynamics. Different scaling regimes are predicted for the evolution of the system's structural relaxation time τ\tau with age (waiting time twt_w), depending on the depth of the quench from the liquid into the glass: \emph{simple aging} (τtw\tau\sim t_w) applies for quenches close to the critical point of mode-coupling theory (MCT) and implies \emph{sub-aging} (τ twδ\tau\approx\ t_w^\delta with δ<1\delta<1) as a broad cross-over for quenches to nearly-arrested equilibrium states; \emph{hyper-aging} (or \emph{super-aging}, τtwδ\tau\sim t_w^{\delta'} with δ>1\delta'>1) emerges for quenches deep into the glass. The latter is cut off by non-mean-field fluctuations that we account for within a recent extension of MCT, the stochastic β\beta-relaxation theory (SBR). We exemplify the scaling laws by a schematic model that allows to quantitatively fit recent simulation results for density-quenched hard-sphere-like particles.

Keywords

Cite

@article{arxiv.2202.13384,
  title  = {From sub-aging to hyper-aging in structural glasses},
  author = {Luis F. Elizondo-Aguilera and Tommaso Rizzo and Thomas Voigtmann},
  journal= {arXiv preprint arXiv:2202.13384},
  year   = {2022}
}

Comments

5 pages, 3 figures

R2 v1 2026-06-24T09:55:25.561Z