English

Finite-size effects at first-order isotropic-to-nematic transitions

Statistical Mechanics 2009-06-24 v1

Abstract

We present simulation data of first-order isotropic-to-nematic transitions in lattice models of liquid crystals and locate the thermodynamic limit inverse transition temperature ϵ\epsilon_\infty via finite-size scaling. We observe that the inverse temperature of the specific heat maximum can be consistently extrapolated to ϵ\epsilon_\infty assuming the usual α/Ld\alpha / L^d dependence, with LL the system size, dd the lattice dimension and proportionality constant α\alpha. We also investigate the quantity ϵL,k\epsilon_{L,k}, the finite-size inverse temperature where kk is the ratio of weights of the isotropic to nematic phase. For an optimal value k=koptk = k_{\rm opt}, ϵL,k\epsilon_{L,k} versus LL converges to ϵ\epsilon_\infty much faster than α/Ld\alpha/L^d, providing an economic alternative to locate the transition. Moreover, we find that αlnkopt/L\alpha \sim \ln k_{\rm opt} / {\cal L}_\infty, with L{\cal L}_\infty the latent heat density. This suggests that liquid crystals at first-order IN transitions scale approximately as qq-state Potts models with qkoptq \sim k_{\rm opt}.

Keywords

Cite

@article{arxiv.0906.4166,
  title  = {Finite-size effects at first-order isotropic-to-nematic transitions},
  author = {J. M. Fish and R. L. C. Vink},
  journal= {arXiv preprint arXiv:0906.4166},
  year   = {2009}
}

Comments

To appear in Physical Review B

R2 v1 2026-06-21T13:16:43.506Z