Fidelity Analysis of Adiabatically Driven Donor Spins as Two-Qubit and Ququart Systems

Donor spin systems host a native Hilbert space whose dimension exceeds that of a qubit, meaning they can be used as qudits. Here we study a \ce{Si{:}P} donor spin system through leakage-aware randomized benchmarking (RB) of native ququart $\mathcal{C}_4$ and encoded two-qubit $\mathcal{C}_2^{\otimes 2}$ Clifford groups. We implement adiabatic ramps to operate electron dipole spin resonance (EDSR) pulses at the ionization point, where the electron is shared halfway between the donor and the interface, and to operate electron spin resonance (ESR) pulses near the interface, motivated by the sensitivity of the effective magnetic field to charge noise at the ionization point. By placing the electron near the ionization point only during EDSR control and using sufficiently long displacement ramp durations, leakage outside the computational basis is strongly suppressed, which is crucial for optimized qudit control. We find in our analysis based on leakage RB that $\mathcal{C}_4$ consistently achieves $\sim 40$--$50\%$ lower (lower-bound) error rates $\varepsilon^{\mathrm{LB}}_\mathrm{PT}$ with respect to $\mathcal{C}_2^{\otimes 2}$, due to its reduced circuit complexity. These results indicate that donor spin qudits benefit from genuine qudit operation as opposed to imposed encoded qubit operation.