English

Exceptional Anti-Icing Performance of Self-Impregnating Slippery Surfaces

Soft Condensed Matter 2017-03-23 v1

Abstract

A heat exchange interface at subzero temperature in a water vapor environment, exhibits high probability of frost formation due to freezing condensation, a factor that markedly decreases the heat transfer efficacy due to the considerable thermal resistance of ice. Here we report a novel strategy to delay ice nucleation on these types of solid-water vapor interfaces. With a process-driven mechanism, a self-generated liquid intervening layer immiscible to water, is deposited on a textured superhydrophobic surface and acts as a barrier between the water vapor and the solid substrate. This liquid layer imparts remarkable slippery conditions resulting in high mobility of condensing water droplets. A large increase of the ensuing ice coverage time is shown compared to the cases of standard smooth hydrophilic or textured superhydrophobic surfaces. During deicing of these self-impregnating surfaces we show an impressive tendency of ice fragments to skate expediting defrosting. Robustness of such surfaces is also demonstrated by operating them under subcooling for at least 490hr without a marked degradation. This is attributed to the presence of the liquid intervening layer, which protects the substrate from hydrolyzation enhancing longevity and sustaining heat transfer efficiency.

Keywords

Cite

@article{arxiv.1703.07349,
  title  = {Exceptional Anti-Icing Performance of Self-Impregnating Slippery Surfaces},
  author = {Christos Stamatopoulos and Jaroslav Hemrle and Danhong Wang and Dimos Poulikakos},
  journal= {arXiv preprint arXiv:1703.07349},
  year   = {2017}
}

Comments

This document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Applied Materials & Interfaces, copyright (c) American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see pubs.acs.org/doi/abs/10.1021/acsami.7b00186

R2 v1 2026-06-22T18:52:55.589Z