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Exact Screening-Ranged Expansions for Many-Body Electrostatics

Soft Condensed Matter 2025-12-12 v2 Mathematical Physics math.MP Biological Physics Chemical Physics Computational Physics

Abstract

We present an exact many-body framework for electrostatic interactions among NN arbitrarily charged spheres in an electrolyte, modeled by the linearized Poisson--Boltzmann equation. Building on a spectral analysis of nonstandard Neumann--Poincar\'e-type operators introduced in a companion mathematical work arXiv:2512.08684, we construct convergent screening-ranged series for the potential, interaction energy, and forces, where each term is associated with a well-defined Debye--H\"uckel screening order and can be obtained evaluating an analytical expression rather than numerically solving an infinitely dimensional linear system. This formulation unifies and extends classical and recent approaches, providing a rigorous basis for electrostatic interactions among heterogeneously charged particles (including Janus colloids) and yielding many-body generalizations of analytical explicit-form results previously available only for two-body systems. The framework captures and clarifies complex effects such as asymmetric dielectric screening, opposite-charge repulsion, and like-charge attraction, which remain largely analytically elusive in existing treatments. Beyond its fundamental significance, the method leads to numerically efficient schemes, offering a versatile tool for modeling colloids and soft/biological matter in electrolytic solution.

Keywords

Cite

@article{arxiv.2512.09421,
  title  = {Exact Screening-Ranged Expansions for Many-Body Electrostatics},
  author = {Sergii V. Siryk and Walter Rocchia},
  journal= {arXiv preprint arXiv:2512.09421},
  year   = {2025}
}

Comments

10 pages, 1 figure

R2 v1 2026-07-01T08:18:30.842Z