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CVM studies on the atomic ordering in complex perovskite alloys

Materials Science 2009-10-31 v1 Statistical Mechanics

Abstract

The atomic ordering in complex perovskite alloys is investigated by the cluster variation method (CVM). For the 1/3\{111\}-type ordered structure, the order-disorder phase transition is the first order, and the order parameter of the 1:2 complex perovskite reaches its maximum near x=0.25. For the 1/2\{111\}-type ordered structure, the ordering transition is the second order. Phase diagrams for both ordered structures are obtained. The order-disorder line obeys the linear law.

Cite

@article{arxiv.cond-mat/0005341,
  title  = {CVM studies on the atomic ordering in complex perovskite alloys},
  author = {Zhi-Rong Liu and Jian-She Liu and Bing-Lin Gu and Xiao-Wen Zhang},
  journal= {arXiv preprint arXiv:cond-mat/0005341},
  year   = {2009}
}

Comments

10 pages, 6 figures

R2 v1 2026-07-22T10:03:04.770Z